diff --git a/notes/chem/chem_ap-reference.txt b/notes/chem/chem_ap-reference.txt new file mode 100644 index 0000000..6a3b642 --- /dev/null +++ b/notes/chem/chem_ap-reference.txt @@ -0,0 +1,49 @@ +== CONSTANTS == +h=6.626E-34 J-s (Planck) +c=2.998E8 m/s (speed of light) +N_A=6.022E23 mol-1 (Avogadro) +R=8.314 J/mol-K (gas constant) +R=0.08206 L-atm/mol-K +F=96485 C/mol-e (Faraday) +STP=273.15 K, 1.0 atm, 22.4 L/mol + +== WATER == +K_w=1.0E-14 (at 25 deg C) +pK_w=14 = pH + pOH +K_w = K_a * K_b + +== EQUATIONS == +Ideal gas: P*V = n*R*T +Boyle: P_1*V_1 = P_2*V_2 +Dalton: P_tot = P_A + P_B + P_C +Mole fraction: X_A = moles_A / total_moles +Partial pressure: P_A = P_tot * X_A +Molarity: M = n_solute / L_solution +Density: D = m / V +KE = 0.5*m*v^2 + +== KINETICS == +[A]_t - [A]_0 = -k*t +ln([A]_t/[A]_0) = -k*t +t_1/2 = 0.693/k + +== EQUILIBRIUM == +K = [C]^c*[D]^d / [A]^a*[B]^b +K_p uses partial pressures +pH = -log[H_3O^+] +pOH = -log[OH^-] +pH = pK_a + log(A^-/HA) + +== THERMO == +D_H_rxn = D_H_f_products - D_H_f_reactants +q = m*c*_T +D_S_rxn = D_S_products - D_S_reactants +D_G = D_H - T*D_S +D_G = -R*T*ln(K) +D_G = -n*F*E + +== ELECTRO = +E_cell = E_cath - E_anod +E_cell = E_std - R*T/(n*F)*ln(Q) +E_cell = E_std - 0.0592/n*log(Q) (at 25 deg C) +Q = I*t